Kang Myungshim, Smith Paul E
Department of Chemistry, 111 Willard Hall, Kansas State University, Manhattan, Kansas 66506-3701, USA.
J Chem Phys. 2008 Jun 28;128(24):244511. doi: 10.1063/1.2943318.
Explicit expressions are developed for the chemical potential derivatives, partial molar volumes, and isothermal compressibility of solution mixtures involving four components at finite concentrations using the Kirkwood-Buff theory of solutions. In addition, a general recursion relationship is provided which can be used to generate the chemical potential derivatives for higher component solutions.
利用柯克伍德-布夫溶液理论，推导出了有限浓度下包含四种组分的溶液混合物的化学势导数、偏摩尔体积和等温压缩率的显式表达式。此外，还给出了一个通用的递推关系，可用于生成更高组分溶液的化学势导数。
