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三金属镧系发光阴离子传感器的溶液研究：利用内部参考通道实现比率传感

Solution studies of trimetallic lanthanide luminescent anion sensors: towards ratiometric sensing using an internal reference channel.

作者信息

Plush Sally E, Gunnlaugsson Thorfinnur

机构信息

School of Chemistry, Centre for Synthesis and Chemical Biology, Trinity College Dublin, Dublin 2, Ireland.

出版信息

Dalton Trans. 2008 Aug 7(29):3801-4. doi: 10.1039/b805610b. Epub 2008 Jun 12.

DOI:10.1039/b805610b
PMID:18629401
Abstract

Luminescent europium and terbium complexes and a mixed Eu(III)-Tb(III) complex were prepared, each with three macrocycles coordinating to a single lanthanide ion to form a trimetallic system, and can be used for the ratiometric sensing of anions in the case of the mixed complex.

摘要

制备了发光铕和铽配合物以及一种铕（III）-铽（III）混合配合物，每种配合物都有三个大环与单个镧系离子配位形成三金属体系，对于混合配合物而言，可用于阴离子的比率传感。

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