非共价离子-分子复合物中的气相对映选择性反应。
Gas-phase enantioselective reactions in noncovalent ion-molecule complexes.
作者信息
Speranza Maurizio, Gasparrini Francesco, Botta Bruno, Villani Claudio, Subissati Deborah, Fraschetti Caterina, Subrizi Fabiana
机构信息
Dipartimento degli Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Università di Roma La Sapienza, 00185 Roma, Italy.
出版信息
Chirality. 2009 Jan;21(1):69-86. doi: 10.1002/chir.20606.
Noncovalent diastereomeric ion-molecule complexes are produced in the gas phase and are ideal for the study of chiral recognition in the absence of complicating solvent and counterion effects. This review article describes the state-of-art in this field with special emphasis on the most recent mass spectrometric studies of the structure, dynamics, and reactivity of diastereomeric ion/molecule aggregates.
非共价非对映异构离子-分子络合物在气相中产生，是研究手性识别的理想选择，因为不存在复杂的溶剂和抗衡离子效应。这篇综述文章描述了该领域的最新进展，特别强调了对非对映异构离子/分子聚集体的结构、动力学和反应性的最新质谱研究。
Zotero 插件