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通过分析光激发发光、热释光和电子自旋共振检测烘烤前后的γ辐照芝麻籽。

Detection of gamma-irradiated sesame seeds before and after roasting by analyzing photostimulated luminescence, thermoluminescence, and electron spin resonance.

作者信息

Lee Jeongeun, Kausar Tusneem, Kim Byeong-Keun, Kwon Joong-Ho

机构信息

Department of Food Science and Technology, Kyungpook National University, Daegu 702-701, Korea.

出版信息

J Agric Food Chem. 2008 Aug 27;56(16):7184-8. doi: 10.1021/jf801416r. Epub 2008 Jul 26.

DOI:10.1021/jf801416r
PMID:18656935
Abstract

Sesame seeds were irradiated using a (60)Co irradiator (0-4 kGy) and then roasted (220 degrees C for 10 min). To identify the irradiation treatment, physical detection methods like photostimulated luminescence (PSL), thermoluminescence (TL), and electron spin resonance (ESR) have been investigated before and after roasting. The photon counts of the irradiated samples (nonroasted and roasted) were higher than those of nonirradiated ones, making it possible to distinguish the two samples. The threshold values of nonroasted and roasted samples increased linearly with the irradiation dose, respectively. The TL for the nonirradiated nonroasted and roasted samples presented a lower peak at about 300 degrees C, but irradiated samples showed a higher peak at around 150 degrees C. The areas of TL glow curves were 15 times higher in nonroasted as compared with roasted samples. TL ratio [integrated area of TL 1 (the first glow)/TL 2 (the second glow)] obtained by the reirradiation step was 0 in nonirradiated samples and more than 0.15 in irradiated samples. The radiation-induced ESR signals originating from cellulose were determined in irradiated samples before and after roasting.

摘要

芝麻籽使用钴 - 60辐照器(0 - 4千戈瑞)进行辐照,然后烘焙(220摄氏度,10分钟)。为了识别辐照处理,在烘焙前后研究了光激发发光(PSL)、热释光(TL)和电子自旋共振(ESR)等物理检测方法。辐照样品(未烘焙和烘焙后的)的光子计数高于未辐照样品,从而能够区分这两种样品。未烘焙和烘焙样品的阈值分别随辐照剂量呈线性增加。未辐照的未烘焙和烘焙样品的热释光在约300摄氏度处呈现较低峰值,但辐照样品在约150摄氏度处显示较高峰值。未烘焙样品的热释光发光曲线面积比烘焙样品高15倍。通过再辐照步骤获得的热释光比率[热释光1(第一次发光)/热释光2(第二次发光)的积分面积]在未辐照样品中为0,在辐照样品中大于0.15。在烘焙前后的辐照样品中测定了源自纤维素的辐射诱导电子自旋共振信号。

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