Dornan Peter, Rowley Christopher N, Priem Jessica, Barry Seán T, Burchell Tara J, Woo Tom K, Richeson Darrin S
Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, Ottawa, Ontario, CanadaK1N 6N5.
Chem Commun (Camb). 2008 Aug 21(31):3645-7. doi: 10.1039/b803732a. Epub 2008 Jun 20.
A novel method for the cyclotrimerization of dimethylcyanamide to form hexamethylmelamine has been developed using an aluminium amide catalyst; detailed DFT modelling of the catalytic cycle supports a triple insertion, nucleophilic ring closure, deinsertion mechanism.
已开发出一种使用铝酰胺催化剂将二甲基氰胺环三聚化以形成六甲基三聚氰胺的新方法；对催化循环的详细密度泛函理论建模支持三插入、亲核环化、脱插入机制。
