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用于改变生物质衍生含氧烃的能量含量并实现碳-碳偶联的催化策略。

Catalytic strategies for changing the energy content and achieving C--C coupling in biomass-derived oxygenated hydrocarbons.

作者信息

Simonetti Dante A, Dumesic James A

机构信息

Department of Chemical and Biological Engineering, University of Wisconsin, Madison, WI 53706, USA.

出版信息

ChemSusChem. 2008;1(8-9):725-33. doi: 10.1002/cssc.200800105.

Abstract

This Concept examines the opportunities for the use of biomass feedstocks in the production of liquid fuels for the transportation sector of society. The cost-competitive conversion of biomass into liquid fuels involves the integration of processes that operate on lignocellulosic feeds with processes that convert specific fractions of lignocellulose. A brief description of current energy systems is given to indicate the potential contributions of biomass to replace fossil fuel feedstocks for energy production, followed by a description of current biomass-conversion technologies. Specific focus is given to promising reaction pathways and novel research opportunities for conversion of the carbohydrate fraction of lignocellulose into fuels with targeted structures.

摘要

本概念探讨了在社会交通部门的液体燃料生产中使用生物质原料的机会。将生物质转化为具有成本竞争力的液体燃料涉及到对木质纤维素原料进行处理的工艺与转化木质纤维素特定部分的工艺的整合。文中简要介绍了当前的能源系统,以表明生物质在替代化石燃料原料用于能源生产方面的潜在贡献,随后描述了当前的生物质转化技术。特别关注了将木质纤维素碳水化合物部分转化为具有特定结构燃料的有前景的反应途径和新的研究机会。

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