Price Mortimer Anne J, Pang Pui Shan, Aliev Abil E, Tocher Derek A, Porter Michael J
Department of Chemistry, University College London, Christopher Ingold Building, 20 Gordon Street, London, UKWC1H 0AJ.
Org Biomol Chem. 2008 Aug 21;6(16):2941-51. doi: 10.1039/b806031b. Epub 2008 Jun 19.
A number of bicyclic aminals have been prepared in a stereospecific manner as potential precursors to the core structure of the sarain alkaloids. Rearrangement of these aminals to new diazabicyclic and diazatricyclic systems has been observed under various conditions.
已经以立体专一的方式制备了许多双环缩醛胺，作为沙林生物碱核心结构的潜在前体。在各种条件下，已观察到这些缩醛胺重排为新的二氮杂双环和二氮杂三环体系。
