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具有高机械强度和低高温热导率的透明疏水性复合气凝胶。

Transparent, hydrophobic composite aerogels with high mechanical strength and low high-temperature thermal conductivities.

作者信息

Wei Te-Yu, Lu Shih-Yuan, Chang Yu-Cheng

机构信息

Department of Chemical Engineering, National Tsing-Hua University, HsinChu, Taiwan 30013, Republic of China.

出版信息

J Phys Chem B. 2008 Sep 25;112(38):11881-6. doi: 10.1021/jp804855v. Epub 2008 Aug 27.

Abstract

A facile one-step polymer-incorporation sol-gel process, together with a surface modification and an ambient pressure drying processes, was developed to prepare silica-poly(vinylpyrrolidone) composite aerogels. These composite aerogels are with high hydrophobicity (static contact angle >120 degrees), good mechanical strength (Young's modulus of bending >30 MPa), and low high-temperature thermal conductivity (0.063 W/m-K at 300 degrees C), which are critical characteristics for practical applications of aerogels, particularly in energy saving areas, for long-term usage and large scale production.

摘要

一种简便的一步聚合物掺入溶胶-凝胶法,结合表面改性和常压干燥工艺,被开发用于制备二氧化硅-聚(乙烯基吡咯烷酮)复合气凝胶。这些复合气凝胶具有高疏水性(静态接触角>120度)、良好的机械强度(弯曲杨氏模量>30MPa)和低高温热导率(300摄氏度时为0.063W/m-K),这些是气凝胶实际应用的关键特性,特别是在节能领域,可长期使用并大规模生产。

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