钒催化内消旋仲烯丙醇和高烯丙醇的对映选择性去对称化反应。
Vanadium-catalyzed enantioselective desymmetrization of meso secondary allylic alcohols and homoallylic alcohols.
作者信息
Li Zhi, Zhang Wei, Yamamoto Hisashi
机构信息
Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, IL 60637, USA.
出版信息
Angew Chem Int Ed Engl. 2008;47(39):7520-2. doi: 10.1002/anie.200802523.
Abstract
has extended substrate scope. In addition to various bis-allylic alcohols, bis-homoallylic alcohols can also be desymmetrized using our Vanadium-Bis-hydroxamic acid complexes.
摘要
具有扩展的底物范围。除了各种双烯丙基醇外，双高烯丙基醇也可以使用我们的钒-双异羟肟酸配合物进行去对称化。
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