Yam Vivian Wing-Wah, Cheng Eddie Chung-Chin
Centre for Carbon-Rich Molecular and Nano-Scale Metal-Based Materials Research, Department of Chemistry, and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China.
Chem Soc Rev. 2008 Sep;37(9):1806-13. doi: 10.1039/b708615f. Epub 2008 Jul 9.
The presence of inter- and/or intra-molecular aurophilic interactions among the closed-shell gold(I) centres in various systems has been studied from various aspects, including synthetic, spectroscopic and theoretical approaches. The employment of different ligands can impose a significant influence on these factors and give rise to new complexes with interesting structural and photophysical properties. In this tutorial review, a number of recent examples are selected to illustrate the fascinating properties and chemistry, as well as versatility of gold(I) in these aspects and their potential applications to newcomers in this field. An emerging class of luminescent gold(III) complexes is also described.
人们已从多个方面研究了各种体系中闭壳层金（I）中心之间分子间和/或分子内亲金相互作用的存在情况，包括合成、光谱和理论方法。使用不同的配体可对这些因素产生重大影响，并产生具有有趣结构和光物理性质的新配合物。在本专题综述中，选取了一些近期的例子来说明金（I）在这些方面迷人的性质、化学特性以及多功能性，及其在该领域新手眼中的潜在应用。还介绍了一类新兴的发光金（III）配合物。
