Katz Michael J, Sakai Ken, Leznoff Daniel B
Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia, Canada V5A 1S6.
Chem Soc Rev. 2008 Sep;37(9):1884-95. doi: 10.1039/b709061g. Epub 2008 Jul 21.
Research in the field of supramolecular chemistry has rapidly grown in recent years due to the generation of fascinating structural topologies and their associated physical properties. In order to rationally synthesize such high-dimensionality systems, several different classes of non-covalent intermolecular interactions in the crystal engineering toolbox can be utilized. Among these, attractive metallophilic interactions, such as those observed for d10 gold(I), have been increasingly harnessed as a design element to synthesize functional high-dimensional systems. This tutorial review will explore the methods by which gold(I) and other d10 and d8 metal centres have been employed to increase structural dimensionality via the formation of metal-metal interactions. Physical and optical properties associated with metallophilicity-based supramolecular structures will also be highlighted.
近年来，由于超分子化学领域产生了引人入胜的结构拓扑及其相关物理性质，该领域的研究迅速发展。为了合理地合成此类高维体系，可以利用晶体工程工具箱中的几种不同类型的非共价分子间相互作用。其中，有吸引力的亲金属相互作用，如在d10金（I）中观察到的那些，越来越多地被用作设计元素来合成功能性高维体系。本教程综述将探讨通过形成金属-金属相互作用，利用金（I）以及其他d10和d8金属中心来增加结构维度的方法。还将重点介绍基于亲金属性的超分子结构的物理和光学性质。
