Zhang Yejian, Yan Li, Chi Lina, Long Xiuhua, Mei Zhijian, Zhang Zhenjia
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
J Environ Sci (China). 2008;20(6):658-63. doi: 10.1016/s1001-0742(08)62109-9.
A bench-scale expanded granular sludge bed (EGSB) reactor was applied to the treatment of palm oil mill effluent (POME). The reactor had been operated continuously at 35 degrees C for 514 d, with organic loading rate (OLR) increased from 1.45 to 17.5 kg COD/(m3 x d). The results showed that the EGSB reactor had good performance in terms of COD removal on the one hand, high COD removal of 91% was obtained at two days' of hydraulic retention time (HRT), and the highest OLR of 17.5 kg COD/(m3 x d). On the other hand, only 46% COD in raw POME was transformed into biogas in which the methane content was about 70% (V/V). A 30-d intermittent experiment indicated that the maximum transformation potential of organic matter in raw POME into methane was 56%. Volatile fatty acid (VFA) accumulation was observed in the later operation stage, and this was settled by supplementing trace metal elements. On the whole, the system exhibited good stability in terms of acidity and alkalinity. Finally, the operational problems inherent in the laboratory scale experiment and the corresponding countermeasures were also discussed.
采用实验室规模的膨胀颗粒污泥床(EGSB)反应器处理棕榈油厂废水(POME)。该反应器在35℃下连续运行514天,有机负荷率(OLR)从1.45 kg COD/(m³·d)提高到17.5 kg COD/(m³·d)。结果表明,EGSB反应器一方面在COD去除方面表现良好,在水力停留时间(HRT)为两天时,COD去除率高达91%,最高OLR为17.5 kg COD/(m³·d)。另一方面,原POME中只有46%的COD转化为沼气,其中甲烷含量约为70%(V/V)。一项为期30天的间歇实验表明,原POME中有机物转化为甲烷的最大潜力为56%。在运行后期观察到挥发性脂肪酸(VFA)积累,通过补充微量金属元素得以解决。总体而言,该系统在酸碱度方面表现出良好的稳定性。最后,还讨论了实验室规模实验中存在的操作问题及相应对策。