Sporer Susan, Goll Christian, Mecke Klaus
Institut für Theoretische Physik, Universität Erlangen-Nürnberg, Staudtstrasse 7, Erlangen, Germany.
Phys Rev E Stat Nonlin Soft Matter Phys. 2008 Jul;78(1 Pt 1):011917. doi: 10.1103/PhysRevE.78.011917. Epub 2008 Jul 24.
We show that Brownian motion is spatially not symmetric for mesoscopic particles embedded in a fluid if the particle is not in thermal equilibrium and its shape is not spherical. In view of applications to molecular motors in biological cells, we sustain nonequilibrium by stopping a nonspherical particle at periodic sites along a filament. Molecular dynamics simulations in a Lennard-Jones fluid demonstrate that directed motion is possible without a ratchet potential or temperature gradients if the asymmetric nonequilibrium relaxation process is hindered by external stopping. Analytical calculations in the ideal gas limit show that motion even against a fluid drift is possible and that the direction of motion can be controlled by the shape of the particle, which is completely characterized by tensorial Minkowski functionals.
我们表明,如果嵌入流体中的介观粒子处于非热平衡状态且形状不是球形,那么布朗运动在空间上是不对称的。考虑到在生物细胞中分子马达的应用,我们通过将非球形粒子沿细丝在周期性位置处停止来维持非平衡状态。在 Lennard-Jones 流体中的分子动力学模拟表明,如果不对称非平衡弛豫过程受到外部停止的阻碍,那么在没有棘轮势或温度梯度的情况下也可能产生定向运动。在理想气体极限下的解析计算表明,即使逆着流体漂移运动也是可能的,并且运动方向可以由粒子的形状控制,而粒子的形状完全由张量闵可夫斯基泛函表征。