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胶体与向列相薄膜的有效相互作用。

Effective interactions of colloids on nematic films.

作者信息

Oettel M, Domínguez A, Tasinkevych M, Dietrich S

机构信息

Johannes-Gutenberg-Universität Mainz, Institut für Physik, WA 331, D-55099 Mainz, Germany.

出版信息

Eur Phys J E Soft Matter. 2009 Feb;28(2):99-111. doi: 10.1140/epje/i2008-10360-1.

Abstract

The elastic and capillary interactions between a pair of colloidal particles trapped on top of a nematic film are studied theoretically for large separations d. The elastic interaction is repulsive and of quadrupolar type, varying as d⁻⁵. For macroscopically thick films, the capillary interaction is likewise repulsive and proportional to d⁻⁵ as a consequence of mechanical isolation of the system comprised of the colloids and the interface. A finite film thickness introduces a nonvanishing force on the system (exerted by the substrate supporting the film) leading to logarithmically varying capillary attractions. However, their strength turns out to be too small to be of importance for the recently observed pattern formation of colloidal droplets on nematic films.

摘要

理论上研究了被困在向列相薄膜顶部的一对胶体颗粒之间的弹性和毛细相互作用,研究范围为大间距d。弹性相互作用是排斥性的,呈四极型,随d⁻⁵变化。对于宏观厚度的薄膜,由于由胶体和界面组成的系统的机械隔离,毛细相互作用同样是排斥性的,且与d⁻⁵成正比。有限的薄膜厚度会对系统产生非零力(由支撑薄膜的基板施加),导致毛细吸引力呈对数变化。然而,其强度太小,对于最近在向列相薄膜上观察到的胶体液滴图案形成并不重要。

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