Guo Jun, Mao Jincheng
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou, China.
Chirality. 2009 Jun;21(6):619-27. doi: 10.1002/chir.20661.
A new bifunctional copper-based catalytic system has been developed from readily available salen ligand 7 together with Cu(OAc)(2).H(2)O in situ for asymmetric nitro-aldol reactions between nitromethane and aldehydes, affording corresponding adducts with moderate to good yields and enantioselectivities.
一种新型双功能铜基催化体系已由易于获得的salen配体7与Cu(OAc)₂·H₂O原位反应制得，用于硝基甲烷与醛之间的不对称硝基-羟醛反应，得到相应的加合物，产率和对映选择性适中至良好。
