Griffiths Peter C, Fallis Ian A, Tatchell Thomas, Bushby Lisa, Beeby Andrew
School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United Kingdom.
Adv Colloid Interface Sci. 2008 Dec 2;144(1-2):13-23. doi: 10.1016/j.cis.2008.08.001. Epub 2008 Aug 20.
Incorporation of d- or f-block metals into ligand systems that renders a metal complex surface-active or drives its partitioning into surfactant phases enables the localisation of chemical functionality at interfaces. This article discusses a number of fundamental aspects of these interesting materials and examines potential applications.
将d族或f族金属引入配体体系,使金属配合物具有表面活性或促使其分配到表面活性剂相中,可实现化学官能团在界面处的定位。本文讨论了这些有趣材料的一些基本方面,并探讨了其潜在应用。