由羰基衍生物一锅法合成烯丙基氯
One-pot formation of allylic chlorides from carbonyl derivatives.
作者信息
Fuchter Matthew J, Levy Jean-Noël
机构信息
Department of Chemistry, Imperial College London, London SW7 2AZ.
出版信息
Org Lett. 2008 Nov 6;10(21):4919-22. doi: 10.1021/ol802026u. Epub 2008 Oct 4.
PMID:18834136
Abstract
An efficient, one-pot method for the conversion of carbonyl electrophiles to allylic chlorides has been developed, by activating magnesium alkoxides in situ using TiCl4.
摘要
通过使用四氯化钛原位活化醇镁，已开发出一种高效的一锅法将羰基亲电试剂转化为烯丙基氯。
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