Bedford Colin T, Perry David, Sharma Rajnesh K
Department of Chemistry, University College London (UCL), London, UK.
Nat Prod Res. 2008;22(17):1535-9. doi: 10.1080/14786410802176737.
A mycelial co-metabolite of strobilurin A, F and G from Bolinea lutea, which we have named bolineol, has been characterised for the first time. Bolineol (methyl 2-hydroxymethyl-3-methyl-6-phenyl-3Z,5E-hexadienoate) has a similar carbon skeleton to strobilurin A but differs in oxidation level. Its structure has been deduced from its spectral characteristics and those of its acetate. The known compound strobilurin F-1 (methyl 2-methoxymethylene-3-methyl-6-(3'-hydroxyphenyl)-3Z,5E-hexadienoate) has been detected in this organism for the first time and converted into its acetate, a new compound, the structure of which was assigned from its spectral data.
首次对来自黄顶耳（Bolinea lutea）的嗜球果伞素A、F和G的一种菌丝体共代谢产物进行了表征，我们将其命名为黄顶耳醇。黄顶耳醇（2-羟甲基-3-甲基-6-苯基-3Z,5E-己二烯酸甲酯）与嗜球果伞素A具有相似的碳骨架，但氧化水平不同。其结构已根据其光谱特征及其乙酸酯的光谱特征推导得出。已知化合物嗜球果伞素F-1（2-甲氧基亚甲基-3-甲基-6-(3'-羟基苯基)-3Z,5E-己二烯酸甲酯）首次在该生物体中被检测到，并转化为其乙酸酯，这是一种新化合物，其结构已根据光谱数据确定。
