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由光控制和驱动的人工酶催化。

Artificial enzyme catalysis controlled and driven by light.

作者信息

Knör Günther

机构信息

Institut für Anorganische Chemie, Johannes Kepler Universität Linz, 4040 Linz, Austria.

出版信息

Chemistry. 2009;15(3):568-78. doi: 10.1002/chem.200801179.

Abstract

Bio-inspired chemistry based on photoresponsive molecules is a rapidly developing new strategy to mimic the function of various biological systems. The interaction of electromagnetic radiation with molecular systems is ideally suited for the control and powering of dynamic processes at the speed of light. Besides typical applications in artificial photosynthesis, many other aspects, such as the catalytic turnover of substrates or the controlled release or uptake of small bioactive molecules, are readily verified with light-driven model systems. The potential of this novel approach in biomimetic chemistry is briefly explored in this concept article.

摘要

基于光响应分子的仿生化学是一种迅速发展的新策略,用于模拟各种生物系统的功能。电磁辐射与分子系统的相互作用非常适合以光速控制和驱动动态过程。除了在人工光合作用中的典型应用外,许多其他方面,如底物的催化周转或生物活性小分子的可控释放或摄取,都可以通过光驱动模型系统轻松验证。这篇概念文章简要探讨了这种新方法在仿生化学中的潜力。

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