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共振拉曼和共振超拉曼强度:溶液中分子激发态的结构与动力学

Resonance Raman and resonance hyper-Raman intensities: structure and dynamics of molecular excited states in solution.

作者信息

Myers Kelley Anne

机构信息

School of Natural Sciences, University of California, Merced, P.O. Box 2039, Merced, California 95344, USA.

出版信息

J Phys Chem A. 2008 Nov 27;112(47):11975-91. doi: 10.1021/jp805530y.

DOI:10.1021/jp805530y
PMID:18954035
Abstract

Resonance Raman scattering is discussed as a vibronic spectroscopy that can provide detailed information about the structure and dynamics of excited electronic states of molecules. The emphasis is on molecules in liquid solution. The theory of resonance Raman intensities and experimental and interpretive methods are discussed both in a historical context and in their present and future implementations. The related but much less developed technique of two-photon-resonant hyper-Raman scattering is also discussed in a similar context.

摘要

共振拉曼散射作为一种振动光谱学进行了讨论,它可以提供有关分子激发电子态的结构和动力学的详细信息。重点是液态溶液中的分子。在历史背景以及当前和未来的应用中,都讨论了共振拉曼强度理论以及实验和解释方法。还在类似背景下讨论了相关但发展程度低得多的双光子共振超拉曼散射技术。

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