具有多种金属氧化态的N-杂四苯基卟啉铑配合物的合成。

Synthesis of N-confused tetraphenylporphyrin rhodium complexes having versatile metal oxidation states.

作者信息

Srinivasan Alagar, Toganoh Motoki, Niino Teppei, Osuka Atsuhiro, Furuta Hiroyuki

机构信息

Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan.

出版信息

Inorg Chem. 2008 Dec 1;47(23):11305-13. doi: 10.1021/ic061093+.

DOI:10.1021/ic061093+

PMID:18954046

Abstract

A variety of N-confused tetraphenylporphyrin rhodium complexes were synthesized, and their structures and physical properties were investigated. Depending on the reaction conditions, the rhodium(I), -(III), and -(IV) complexes were produced, which exemplified the versatile coordination mode of N-confused porphyrin ligands.

摘要

合成了多种N-混淆四苯基卟啉铑配合物，并对其结构和物理性质进行了研究。根据反应条件，生成了铑（I）、铑（III）和铑（IV）配合物，这些配合物体现了N-混淆卟啉配体多样的配位模式。