Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, Peking University, Beijing, 100871, China.
Chem Commun (Camb). 2010 Sep 14;46(34):6353-5. doi: 10.1039/c0cc01406k. Epub 2010 Aug 12.
Selective oxidation of alcohol in water using molecular oxygen as the terminal oxidant is mediated by rhodium porphyrin complexes. Addition of methanol to an aqueous solution of (TSPP)Rh(III) resulted in observation of the key intermediate porphyrin rhodium(III) methoxide species. The activation parameters for betaC-H elimination of Rh-alkoxide were evaluated.
使用分子氧作为末端氧化剂，通过铑卟啉配合物实现醇的选择性氧化。在(TSPP)Rh(III)的水溶液中加入甲醇，观察到关键的中间物卟啉铑(III)甲氧基物种。评估了 Rh-烷氧基的βC-H 消除的活化参数。
