电位滴定法测定锆和钍与天冬氨酸和谷氨酸形成的螯合物的逐级稳定常数。
Potentiometric determination of stepwise stability constants of zirconium and thorium chelates formed with aspartic and glutamic acids.
作者信息
Singh M K, Srivastava M N
机构信息
Chemical Laboratories University of Allahabad AllahabadIndia.
出版信息
Talanta. 1972 May;19(5):699-700. doi: 10.1016/0039-9140(72)80212-1.
The metal chelates of Zr(IV) and Th(IV) with aspartic and glutamic acids have been studied potentiometrically. Stepwise stability constants in 0.1 M sodium perchlorate at 25 degrees are reported as: aspartate chelates-log K(1) 9.70, log K(2) 6.85, and log K(3) 3.50 for Zr, and log k(1) 9.23, log K(2) 8.57, log K(3) 4.55 and log K(4) 3.87 for Th; glutamate chelates-log K(1) 9.60, log K(2) 6.40 and log K(3) 3.32 for Zr and log K(1) 9.11, log K(2) 8.52, log K(3) 4.18 and log K(4) 3.62 for Th.
已用电位分析法研究了锆（IV）和钍（IV）与天冬氨酸和谷氨酸形成的金属螯合物。报告了在25℃下0.1M高氯酸钠中的逐级稳定常数：天冬氨酸螯合物——锆的log K(1)为9.70，log K(2)为6.85，log K(3)为3.50；钍的log k(1)为9.23，log K(2)为8.57，log K(3)为4.55，log K(4)为3.87；谷氨酸螯合物——锆的log K(1)为9.60，log K(2)为6.40，log K(3)为3.32；钍的log K(1)为9.11，log K(2)为8.52，log K(3)为4.18，log K(4)为3.62。
Zotero 插件