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9,10-双[双(β-羟乙基)氨甲基]蒽的络合和荧光行为。

Complexation and fluorescence behavior of 9,10-bis[bis(beta-hydroxyethyl)aminomethyl]anthracene.

机构信息

Institute of Advanced Material Study, 86, Kyushu University, Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan.

出版信息

Talanta. 1999 Aug 23;50(1):73-7. doi: 10.1016/s0039-9140(99)00109-5.

DOI:10.1016/s0039-9140(99)00109-5
PMID:18967696
Abstract

9,10-Bis[bis(beta-hydroxyethyl)aminomethyl]anthracene (1) showed weak emission, suggesting that photoinduced electron transfer (PET) from amine group to excited anthracene occur. The PET fluoroionophore (1) was found to display unique photophysical properties in the presence of the guest metal cations in H(2)OCH(3)OH (1:1, v/v). Complexation of 1 with guest metal cations increased the fluorescence intensity.

摘要

9,10-双[双(β-羟乙基)氨基甲基]蒽(1)的发射较弱,表明从胺基到激发蒽的光诱导电子转移(PET)发生。在 H(2)OCH(3)OH(1:1,v/v)中存在客体金属阳离子时,发现 PET 荧光体(1)具有独特的光物理性质。1 与客体金属阳离子的络合增加了荧光强度。

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