Stratingh Institute for Chemistry, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.
J Org Chem. 2008 Dec 5;73(23):9482-5. doi: 10.1021/jo801588d.
An efficient method has been developed for the reduction of carbon-carbon double bonds with diimide, catalytically generated in situ from hydrazine hydrate. The employed catalyst is prepared in one step from riboflavin (vitamin B(2)). Reactions are carried out in air and are a valuable alternative when metal-catalyzed hydrogenations are problematic.
一种高效的方法已经被开发出来，用于通过肼水合作用原位催化生成的二酰亚胺还原碳-碳双键。所使用的催化剂可以一步从核黄素（维生素 B(2)）制备得到。反应可以在空气中进行，当金属催化氢化存在问题时，这是一种很有价值的替代方法。
