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碱性离子液体[bmIm]OH催化超声促进肟的合成。

Ultrasound-promoted synthesis of oximes catalyzed by a basic ionic liquid [bmIm]OH.

作者信息

Zang Hongjun, Wang Meiling, Cheng Bo-Wen, Song Jun

机构信息

Department of Material Science and Chemistry Engineering, Tianjin Polytechnic University, Tianjin Municipal Key Laboratory of Fiber Modification and Functional Fiber, Tianjin 300160, China.

出版信息

Ultrason Sonochem. 2009 Mar;16(3):301-3. doi: 10.1016/j.ultsonch.2008.09.003. Epub 2008 Sep 26.

Abstract

The basic ionic liquid 1-butyl-3-methylimidazolium hydroxide, [bmIm]OH, efficiently catalyzes the condensation reaction of aldehydes and ketones with hydroxylamine hydrochloride under ultrasound irradiation. Compared with conventional methods, the main advantages of the present procedure are milder conditions, shorter reaction time and higher yields.

摘要

碱性离子液体1-丁基-3-甲基咪唑氢氧化合物,[bmIm]OH,在超声辐射下能有效催化醛、酮与盐酸羟胺的缩合反应。与传统方法相比,本方法的主要优点是反应条件更温和、反应时间更短且产率更高。

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