聚硅氧烷凝胶中的封装分子催化剂：钌簇催化的烯烃异构化反应

Encapsulated molecular catalysts in polysiloxane gels: ruthenium cluster-catalyzed isomerization of alkenes.

作者信息

Motoyama Yukihiro, Abe Motonori, Kamo Kazuyuki, Kosako Yusuke, Nagashima Hideo

机构信息

Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka, Japan.

出版信息

Chem Commun (Camb). 2008 Nov 14(42):5321-3. doi: 10.1039/b809937e. Epub 2008 Sep 17.

DOI:10.1039/b809937e

PMID:18985197

Abstract

Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (mu(3),eta(2),eta(3),eta(5)-acenaphthylene)Ru(3)(CO)(7), and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species.

摘要

新型包钌聚硅氧烷凝胶是通过在（μ(3),η(2),η(3),η(5)-苊烯基）Ru(3)(CO)(7)存在下用二醇处理聚甲基氢硅氧烷制备的，并且在烯烃异构化反应中作为可重复使用的催化剂，不会有催化剂物种泄漏。