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邻碳硼烷前所未有的空间变形。

Unprecedented steric deformation of ortho-carborane.

作者信息

Hutton Brian W, MacIntosh Fraser, Ellis David, Herisse Fabien, Macgregor Stuart A, McKay David, Petrie-Armstrong Victoria, Rosair Georgina M, Perekalin Dmitry S, Tricas Hugo, Welch Alan J

机构信息

Department of Chemistry, School of Engineering & Physical Sciences, Heriot-Watt University, Edinburgh, UK.

出版信息

Chem Commun (Camb). 2008 Nov 14(42):5345-7. doi: 10.1039/b810702e. Epub 2008 Sep 19.

DOI:10.1039/b810702e
PMID:18985205
Abstract

The reduction and subsequent oxidation of meta-carboranes containing bulky groups attached to the cage C atoms affords sterically-crowded ortho-carboranes with unprecedentedly long C-C connectivities.

摘要

含有连接在笼状碳原子上的庞大基团的间碳硼烷的还原及随后的氧化反应，得到了具有前所未有的长碳 - 碳连接性的空间拥挤的邻碳硼烷。

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