二硼烯四氨基苝（DIBOTAP）：一类具有N-B-N单元的新型高荧光功能性多环芳烃。
Diborylenetetraaminoperylenes (DIBOTAP): a new class of highly fluorescent functional polycyclic aromatic hydrocarbons with N-B-N units.
作者信息
Riehm Till, De Paoli Gabriele, Wadepohl Hubert, De Cola Luisa, Gade Lutz H
机构信息
Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, Heidelberg, Germany.
出版信息
Chem Commun (Camb). 2008 Nov 14(42):5348-50. doi: 10.1039/b811864g. Epub 2008 Sep 19.
DOI:10.1039/b811864g
PMID:18985206
Abstract
A new class of N-B-N functionalized perylenes derived from N,N',N",N"'-diborylene-3,4,9,10-tetraaminoperylene (DIBOTAP) is readily accessible via several synthetic routes; they display intense green fluorescence and undergo two electrochemically reversible one-electron oxidation steps at approximately -0.2 V and 0.3 V (vs. SCE).
摘要
一类新型的由N,N',N",N"'-二硼烯-3,4,9,10-四氨基苝（DIBOTAP）衍生而来的N-B-N官能化苝，可通过多种合成路线轻松获得；它们呈现出强烈的绿色荧光，并在大约-0.2 V和0.3 V（相对于饱和甘汞电极）处经历两个电化学可逆的单电子氧化步骤。
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