呋喃镁化反应的结构复杂性：一种具有类亚卟啉Mg3(2,5-呋喃二基)3子结构的十八核产物。
Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like Mg3(2,5-fur-di-yl)3 substructure.
作者信息
Blair Victoria L, Kennedy Alan R, Klett Jan, Mulvey Robert E
机构信息
WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK.
出版信息
Chem Commun (Camb). 2008 Nov 14(42):5426-8. doi: 10.1039/b812147h. Epub 2008 Sep 19.
Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA).Na(CH(2)SiMe(3))(TMP)Mg(TMP)] produces the remarkable dodecasodium-hexamagnesium molecule [{(TMEDA)(3)Na(6)Mg(3)(CH(2)SiMe(3))(2,5-C(4)H(2)O)(3)(2-C(4)H(3)O)(5)}(2)], built upon a bridge network of 10 monodeprotonated and 6 twofold-deprotonated furan ligands.
通过新型杂配烷基酰胺试剂[(TMEDA)·Na(CH₂SiMe₃)(TMP)Mg(TMP)]使呋喃进行钠介导的镁化反应，生成了引人注目的十二钠六镁分子[{(TMEDA)₃Na₆Mg₃(CH₂SiMe₃)₂(2,5-C₄H₂O)₃(2-C₄H₃O)₅}₂]，该分子基于由10个单去质子化和6个双去质子化的呋喃配体构成的桥连网络。
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