金属-烷基键的无限层的合成与表征：解析未溶剂化的碱金属三烷基镁化物的难以捉摸的结构。
Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate.
机构信息
WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK G1 1XL.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):388-90. doi: 10.1039/c0cc02164d. Epub 2010 Aug 31.
PMID:20820529
Abstract
The study of co-complexation reactions between NaCH(2)SiMe(3) and Mg(CH(2)SiMe(3))(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH(2)SiMe(3))(3)}(∞)] (1) as well as the related solvent-free sodium alkyl [{(NaCH(2)SiMe(3))(4)}(∞)] (3).
摘要
研究了 NaCH(2)SiMe(3) 和 Mg(CH(2)SiMe(3))(2) 之间的共配合反应，成功分离并确定了首个无溶剂碱金属烷基镁酸盐 [{NaMg(CH(2)SiMe(3))(3)}(∞)] (1) 的结构，以及相关的无溶剂钠烷基 [{(NaCH(2)SiMe(3))(4)}(∞)] (3)。
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