首例氟烷基化N-杂卟啉镍（II）配合物的合成与反应
Synthesis and reactions of the first fluoroalkylated Ni(II) N-confused porphyrins.
作者信息
Jiang Hua-Wei, Chen Qing-Yun, Xiao Ji-Chang, Gu Yu-Cheng
机构信息
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai, P. R. China.
出版信息
Chem Commun (Camb). 2008 Nov 14(42):5435-7. doi: 10.1039/b811831k. Epub 2008 Sep 22.
DOI:10.1039/b811831k
PMID:18985235
Abstract
The first fluoroalkylated Ni(ii) N-confused porphyrins were synthesized with high regioselectivity and its further alkylation was studied.
摘要
首个氟烷基化的N-杂卟啉镍（II）以高区域选择性合成，并对其进一步的烷基化反应进行了研究。
相似文献
1
Synthesis and reactions of the first fluoroalkylated Ni(II) N-confused porphyrins.首例氟烷基化N-杂卟啉镍（II）配合物的合成与反应
Chem Commun (Camb). 2008 Nov 14(42):5435-7. doi: 10.1039/b811831k. Epub 2008 Sep 22.
2
Electrophilic fluoroalkylation of Ni(II) N-confused porphyrins with fluoroalkylarylsulfonium salts.镍(II) N-稠合卟啉与氟代芳基砜盐的亲电氟烷基化反应。
J Org Chem. 2012 Apr 6;77(7):3604-8. doi: 10.1021/jo3000018. Epub 2012 Mar 15.
3
Endocyclic extension of porphyrin pi-system by interior functionalization of N-confused porphyrins.通过N-杂卟啉的内部官能化实现卟啉π-体系的环内扩展。
Chemistry. 2008;14(34):10585-94. doi: 10.1002/chem.200801156.
4
Calix[4]pyrrole-capped metalloporphyrins as ditopic receptor models for anions.杯[4]吡咯封端的金属卟啉作为阴离子的双位点受体模型。
Org Lett. 2004 Mar 4;6(5):671-4. doi: 10.1021/ol0360750.
5
Metalloporphyrin-capped calix[4]pyrroles: heteroditopic receptor models for anion recognition and ligand fixation.金属卟啉封端的杯[4]吡咯：用于阴离子识别和配体固定的异双位点受体模型
J Org Chem. 2005 Apr 15;70(8):3148-56. doi: 10.1021/jo047993u.
6
Gram-scale synthesis of nickel(II) norcorrole: the smallest antiaromatic porphyrinoid.镍(II)去甲corrole 的克级合成：最小的反芳香卟啉类似物。
Angew Chem Int Ed Engl. 2012 Aug 20;51(34):8542-5. doi: 10.1002/anie.201204395. Epub 2012 Jul 18.
7
Insertion of Ni(I) into Porphyrins at Room Temperature: Preparation of Ni(II)porphyrins, and Ni(II)chlorins and Observation of Hydroporphyrin Intermediates.室温下卟啉环中镍（Ⅱ）的嵌入：镍（Ⅱ）卟啉、镍（Ⅱ）氯卟啉的制备及水卟啉中间体的观察。
Inorg Chem. 2018 Mar 19;57(6):3177-3182. doi: 10.1021/acs.inorgchem.7b03164. Epub 2018 Mar 2.
8
Unprecedented degradation of nickel(II) 2,3,12,13-tetrabromo-5,10,15,20-tetraarylporphyrins by the anion of E-benzaldoxime: a novel approach to nickel(II) chlorophins and bacteriophins.E-苯甲醛肟阴离子对2,3,12,13-四溴-5,10,15,20-四芳基卟啉镍(II)的前所未有的降解：一种合成二氢卟吩镍(II)和细菌卟吩的新方法。
Org Lett. 2009 Jul 2;11(13):2724-7. doi: 10.1021/ol901052w.
9
Facile and efficient hypervalent iodine(III)-mediated meso-functionalization of porphyrins.简便高效的高价碘（III）介导的卟啉中位官能化反应
J Org Chem. 2009 Jan 2;74(1):206-11. doi: 10.1021/jo801855d.
10
Synthesis, electrochemistry, absorption and electro-polymerization of aniline-ethynyl metalloporphyrins.苯胺-乙炔基金属卟啉的合成、电化学、吸收及电聚合
Dalton Trans. 2005 Jan 21(2):396-401. doi: 10.1039/b410416a. Epub 2004 Nov 30.
Zotero 插件