E-苯甲醛肟阴离子对2,3,12,13-四溴-5,10,15,20-四芳基卟啉镍(II)的前所未有的降解：一种合成二氢卟吩镍(II)和细菌卟吩的新方法。
Unprecedented degradation of nickel(II) 2,3,12,13-tetrabromo-5,10,15,20-tetraarylporphyrins by the anion of E-benzaldoxime: a novel approach to nickel(II) chlorophins and bacteriophins.
作者信息
Li Ke-Lai, Guo Can-Cheng, Chen Qing-Yun
机构信息
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.
出版信息
Org Lett. 2009 Jul 2;11(13):2724-7. doi: 10.1021/ol901052w.
PMID:19476341
Abstract
A novel and convenient approach to chlorophins and bacteriophins has been developed through a degradation of nickel(II) 2,3,12,13-tetrabromo-5,10,15,20-tetraarylporphyrins by the anion of E-benzaldoxime. The UV-vis spectra of these chlorophins and bacteriophins are similar to those of metalated chlorin and bacteriochlorin systems but with more intense and bathochromically shifted Q-bands.
摘要
通过E-苯甲醛肟阴离子对2,3,12,13-四溴-5,10,15,20-四芳基卟啉镍(II)进行降解，已开发出一种新颖且便捷的制备二氢卟吩和细菌二氢卟吩的方法。这些二氢卟吩和细菌二氢卟吩的紫外可见光谱与金属化二氢卟吩和细菌二氢卟吩体系的光谱相似，但Q带更强且发生红移。
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