一种用于α-酮膦酸酯不对称硝基醇醛反应的仲胺酰胺有机催化剂。 - Suppr

Suppr

超能文献

A secondary amine amide organocatalyst for the asymmetric nitroaldol reaction of alpha-ketophosphonates.

作者信息

Chen Xiaohong, Wang Jun, Zhu Yin, Shang Deju, Gao Bo, Liu Xiaohua, Feng Xiaoming, Su Zhishan, Hu Changwei

机构信息

Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University.

出版信息

Chemistry. 2008;14(35):10896-9. doi: 10.1002/chem.200801958.

DOI:10.1002/chem.200801958

PMID:18989853

Abstract

摘要

相似文献

A secondary amine amide organocatalyst for the asymmetric nitroaldol reaction of alpha-ketophosphonates.

Chemistry. 2008;14(35):10896-9. doi: 10.1002/chem.200801958.

Recent progress in asymmetric bifunctional catalysis using multimetallic systems.

Acc Chem Res. 2009 Aug 18;42(8):1117-27. doi: 10.1021/ar9000108.

Preparation of asymmetric alpha-ketophosphonates by [3,3]-sigmatropic shift of enolphosphonates.

J Org Chem. 2004 Sep 17;69(19):6500-3. doi: 10.1021/jo049133j.

An asymmetric cyanation reaction and sequential asymmetric cyanation-nitroaldol reaction using a [YLi(3)[tris(binaphthoxide)]] single catalyst component: catalyst tuning with achiral additives.

Angew Chem Int Ed Engl. 2002 Oct 4;41(19):3636-8, 3517. doi: 10.1002/1521-3773(20021004)41:19<3636::AID-ANIE3636>3.0.CO;2-B.

The fluorine-iminium ion gauche effect: proof of principle and application to asymmetric organocatalysis.

Angew Chem Int Ed Engl. 2009;48(17):3065-8. doi: 10.1002/anie.200900405.

Lanthanide (III) salt complexes: arrayed acid-base networks for enantioselective catalysis. The nitroaldol reaction upon aldehydes and trifluoromethylketones.

Chirality. 2009 Oct;21(9):836-42. doi: 10.1002/chir.20698.

Asymmetric nitroaldol reaction. Synthesis of taxotere side chain and (-)-bestatin using (1R)-8-phenylmenthyl glyoxylate.

J Org Chem. 2004 Apr 16;69(8):2844-50. doi: 10.1021/jo0358269.

A designer axially chiral amino sulfonamide as an efficient organocatalyst for direct asymmetric anti-selective Mannich reactions and syn-selective cross-aldol reactions.

Chemistry. 2009 Jul 6;15(27):6678-87. doi: 10.1002/chem.200900267.

Enantioselective nitroaldol reaction catalyzed by sterically modified salen-chromium complexes.

J Org Chem. 2009 Jan 16;74(2):753-6. doi: 10.1021/jo802107b.

N-primary-amine-terminal beta-turn tetrapeptides as organocatalysts for highly enantioselective aldol reaction.

J Org Chem. 2009 Jul 3;74(13):4812-8. doi: 10.1021/jo9005766.

引用本文的文献

Isothiourea-catalysed enantioselective synthesis of phosphonate-functionalised β-lactones.

Chem Sci. 2025 Mar 6;16(16):6828-6836. doi: 10.1039/d5sc00322a. eCollection 2025 Apr 16.

Catalytic enantioselective Henry reaction of α-keto esters, 2-acylpyridines and 2-acylpyridine -oxides.

RSC Adv. 2018 Mar 5;8(17):9414-9422. doi: 10.1039/c8ra00552d. eCollection 2018 Feb 28.

Asymmetric Henry Reaction of 2-Acylpyridine -Oxides Catalyzed by a Ni-Aminophenol Sulfonamide Complex: An Unexpected Mononuclear Catalyst.

Molecules. 2019 Apr 14;24(8):1471. doi: 10.3390/molecules24081471.

Organocatalytic asymmetric Henry reaction of 1H-pyrrole-2,3-diones with bifunctional amine-thiourea catalysts bearing multiple hydrogen-bond donors.

Beilstein J Org Chem. 2016 Feb 16;12:295-300. doi: 10.3762/bjoc.12.31. eCollection 2016.

Quinidine thiourea-catalyzed enantioselective synthesis of β-nitrophosphonates: Beneficial effects of molecular sieves.

Tetrahedron. 2011 Sep 30;67(39):7479-7484. doi: 10.1016/j.tet.2011.07.059.

Organocatalytic High Enantioselective Synthesis of β-Formyl-α-hydroxyphosphonates.

Adv Synth Catal. 2011 Jun 30;353(10):1729-1734. doi: 10.1002/adsc.201000835.

Quantum mechanical investigations of organocatalysis: mechanisms, reactivities, and selectivities.

Chem Rev. 2011 Aug 10;111(8):5042-137. doi: 10.1021/cr100212h. Epub 2011 Jun 28.

Computational investigations of the stereoselectivities of proline-related catalysts for aldol reactions.

J Mol Catal A Chem. 2010 Jun 1;324(1-2):31-38. doi: 10.1016/j.molcata.2010.03.020.

Squaramide-catalyzed enantioselective Michael addition of diphenyl phosphite to nitroalkenes.

Angew Chem Int Ed Engl. 2010;49(1):153-6. doi: 10.1002/anie.200904779.

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型，支持多种主流文档格式。

立即体验

A secondary amine amide organocatalyst for the asymmetric nitroaldol reaction of alpha-ketophosphonates.

作者信息

Chen Xiaohong, Wang Jun, Zhu Yin, Shang Deju, Gao Bo, Liu Xiaohua, Feng Xiaoming, Su Zhishan, Hu Changwei

机构信息

Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University.

出版信息

Chemistry. 2008;14(35):10896-9. doi: 10.1002/chem.200801958.

DOI:10.1002/chem.200801958

PMID:18989853

Abstract

摘要

相似文献

A secondary amine amide organocatalyst for the asymmetric nitroaldol reaction of alpha-ketophosphonates.

Chemistry. 2008;14(35):10896-9. doi: 10.1002/chem.200801958.

Recent progress in asymmetric bifunctional catalysis using multimetallic systems.

Acc Chem Res. 2009 Aug 18;42(8):1117-27. doi: 10.1021/ar9000108.

Preparation of asymmetric alpha-ketophosphonates by [3,3]-sigmatropic shift of enolphosphonates.

J Org Chem. 2004 Sep 17;69(19):6500-3. doi: 10.1021/jo049133j.

An asymmetric cyanation reaction and sequential asymmetric cyanation-nitroaldol reaction using a [YLi(3)[tris(binaphthoxide)]] single catalyst component: catalyst tuning with achiral additives.

Angew Chem Int Ed Engl. 2002 Oct 4;41(19):3636-8, 3517. doi: 10.1002/1521-3773(20021004)41:19<3636::AID-ANIE3636>3.0.CO;2-B.

The fluorine-iminium ion gauche effect: proof of principle and application to asymmetric organocatalysis.

Angew Chem Int Ed Engl. 2009;48(17):3065-8. doi: 10.1002/anie.200900405.

Lanthanide (III) salt complexes: arrayed acid-base networks for enantioselective catalysis. The nitroaldol reaction upon aldehydes and trifluoromethylketones.

Chirality. 2009 Oct;21(9):836-42. doi: 10.1002/chir.20698.

Asymmetric nitroaldol reaction. Synthesis of taxotere side chain and (-)-bestatin using (1R)-8-phenylmenthyl glyoxylate.

J Org Chem. 2004 Apr 16;69(8):2844-50. doi: 10.1021/jo0358269.

A designer axially chiral amino sulfonamide as an efficient organocatalyst for direct asymmetric anti-selective Mannich reactions and syn-selective cross-aldol reactions.

Chemistry. 2009 Jul 6;15(27):6678-87. doi: 10.1002/chem.200900267.

Enantioselective nitroaldol reaction catalyzed by sterically modified salen-chromium complexes.

J Org Chem. 2009 Jan 16;74(2):753-6. doi: 10.1021/jo802107b.

N-primary-amine-terminal beta-turn tetrapeptides as organocatalysts for highly enantioselective aldol reaction.

J Org Chem. 2009 Jul 3;74(13):4812-8. doi: 10.1021/jo9005766.

引用本文的文献

Isothiourea-catalysed enantioselective synthesis of phosphonate-functionalised β-lactones.

Chem Sci. 2025 Mar 6;16(16):6828-6836. doi: 10.1039/d5sc00322a. eCollection 2025 Apr 16.

Catalytic enantioselective Henry reaction of α-keto esters, 2-acylpyridines and 2-acylpyridine -oxides.

RSC Adv. 2018 Mar 5;8(17):9414-9422. doi: 10.1039/c8ra00552d. eCollection 2018 Feb 28.

Asymmetric Henry Reaction of 2-Acylpyridine -Oxides Catalyzed by a Ni-Aminophenol Sulfonamide Complex: An Unexpected Mononuclear Catalyst.

Molecules. 2019 Apr 14;24(8):1471. doi: 10.3390/molecules24081471.

Organocatalytic asymmetric Henry reaction of 1H-pyrrole-2,3-diones with bifunctional amine-thiourea catalysts bearing multiple hydrogen-bond donors.

Beilstein J Org Chem. 2016 Feb 16;12:295-300. doi: 10.3762/bjoc.12.31. eCollection 2016.

Quinidine thiourea-catalyzed enantioselective synthesis of β-nitrophosphonates: Beneficial effects of molecular sieves.

Tetrahedron. 2011 Sep 30;67(39):7479-7484. doi: 10.1016/j.tet.2011.07.059.

Organocatalytic High Enantioselective Synthesis of β-Formyl-α-hydroxyphosphonates.

Adv Synth Catal. 2011 Jun 30;353(10):1729-1734. doi: 10.1002/adsc.201000835.

Quantum mechanical investigations of organocatalysis: mechanisms, reactivities, and selectivities.

Chem Rev. 2011 Aug 10;111(8):5042-137. doi: 10.1021/cr100212h. Epub 2011 Jun 28.

Computational investigations of the stereoselectivities of proline-related catalysts for aldol reactions.

J Mol Catal A Chem. 2010 Jun 1;324(1-2):31-38. doi: 10.1016/j.molcata.2010.03.020.

Squaramide-catalyzed enantioselective Michael addition of diphenyl phosphite to nitroalkenes.

Angew Chem Int Ed Engl. 2010;49(1):153-6. doi: 10.1002/anie.200904779.