从穿心莲地上部分分离得到的两种新的对映-贝壳杉烷二萜糖苷。

Two new ent-labdane diterpenoid glycosides from the aerial parts of Andrographis paniculata.

作者信息

Zhou Kai-Lan, Chen Li-Xia, Zhuang Yu-Lei, Wang Nai-Li, Yao Xin-Sheng, Qiu Feng

机构信息

Department of Natural Products Chemistry, School of Traditional Chinese Materia Medica, Shenyang Pharmaceutical University, Shenyang, China.

出版信息

J Asian Nat Prod Res. 2008 Sep-Oct;10(9-10):939-43. doi: 10.1080/10286020802217432.

DOI:10.1080/10286020802217432

PMID:19003612

Abstract

Two new ent-labdane diterpenoid glycosides were isolated from the aerial parts of Andrographis paniculata. Their structures were elucidated as 3-O-beta-D-glucosyl-14-deoxyandrographiside (1) and 3-O-beta-D-glucosyl-14-deoxy-11,12-didehydroandrographiside (2) by means of 1D and 2D NMR spectral and chemical methods.

摘要

从穿心莲地上部分分离得到两个新的对映-贝壳杉烷二萜糖苷。通过一维和二维核磁共振光谱及化学方法确定它们的结构分别为3-O-β-D-葡萄糖基-14-脱氧穿心莲内酯（1）和3-O-β-D-葡萄糖基-14-脱氧-11,12-二脱氢穿心莲内酯（2）。