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κ-、ι-和λ-角叉菜胶的新型凝胶体系及其与纤维素在离子液体中的复合凝胶

Novel gelling systems of kappa-, iota- and lambda-carrageenans and their composite gels with cellulose using ionic liquid.

作者信息

Prasad Kamalesh, Kaneko Yoshiro, Kadokawa Jun-ichi

机构信息

Department of Nanostructured and Advanced Materials Graduate School of Science and Engineering Kagoshima University, Korimoto, Kagoshima, Japan.

出版信息

Macromol Biosci. 2009 Apr 8;9(4):376-82. doi: 10.1002/mabi.200800179.


DOI:10.1002/mabi.200800179
PMID:19003847
Abstract

Gels of three types of carrageenans (kappa-, iota- and lambda-), as well as their composite gels with cellulose, were prepared using an ionic liquid, 1-butyl-3-methylimidazolium chloride (BMIMCl), by a heating-cooling process. kappa-Carrageenan gave the formation of hard gel while the other two carrageenans gave the formation of softer gels with BMIMCl. The gels were characterized by X-ray diffraction (XRD), thermal analysis (TGA and DSC), scanning electron microscope (SEM) and compressive testing. The results indicated that, among the three types of carrageenans, kappa- and iota-carrageenans gave better miscible gels with BMIMCl, followed by lambda-carrageenan. On the other hand, lambda-carrageenan gave a better miscible composite gel with cellulose and BMIMCl, followed by iota- and kappa-carrageenans. The stress-strain curves indicated that the mechanical properties of the above gel systems on the compressive mode were much better than those of the hydrogels of kappa- and iota-carrageenans as well as the cellulose gel with BMIMCl.

摘要

使用离子液体1-丁基-3-甲基咪唑氯盐(BMIMCl),通过加热-冷却过程制备了三种角叉菜胶(κ-、ι-和λ-)的凝胶,以及它们与纤维素的复合凝胶。κ-角叉菜胶形成硬凝胶,而其他两种角叉菜胶与BMIMCl形成较软的凝胶。通过X射线衍射(XRD)、热分析(TGA和DSC)、扫描电子显微镜(SEM)和压缩测试对凝胶进行了表征。结果表明,在三种角叉菜胶中,κ-和ι-角叉菜胶与BMIMCl形成的凝胶互溶性更好,其次是λ-角叉菜胶。另一方面,λ-角叉菜胶与纤维素和BMIMCl形成的复合凝胶互溶性更好,其次是ι-和κ-角叉菜胶。应力-应变曲线表明,上述凝胶体系在压缩模式下的力学性能远优于κ-和ι-角叉菜胶的水凝胶以及含BMIMCl的纤维素凝胶。

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Novel gelling systems of kappa-, iota- and lambda-carrageenans and their composite gels with cellulose using ionic liquid.

Macromol Biosci. 2009-4-8

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