环氧官能化聚（ε-己内酯）：合成与应用
Epoxy functionalised poly(epsilon-caprolactone): synthesis and application.
作者信息
Zhou Jiaxiang, Wang Wenxin, Villarroya Silvia, Thurecht Kristofer J, Howdle Steven M
机构信息
School of Chemistry, University of Nottingham, University Park, Nottingham, UK.
出版信息
Chem Commun (Camb). 2008 Nov 30(44):5806-8. doi: 10.1039/b810297j. Epub 2008 Oct 1.
DOI:10.1039/b810297j
PMID:19009088
Abstract
Glycidol is used as an initiator for ring-opening polymerisation of epsilon-caprolactone (epsilon-CL) to synthesise epoxy-functionalised poly(epsilon-caprolactone) (PCL) in a reaction catalysed by lipase, and the epoxy-functionalised PCL was further copolymerised with carbon dioxide or anhydride to produce novel graft or hyperbranched copolymers.
摘要
缩水甘油用作ε-己内酯（ε-CL）开环聚合的引发剂，在脂肪酶催化的反应中合成环氧官能化聚（ε-己内酯）（PCL），并且将环氧官能化PCL进一步与二氧化碳或酸酐共聚以制备新型接枝或超支化共聚物。
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