在氯化锂和氯化锌存在下，通过将镁直接插入苄基氯化物中来制备多官能苄基氯化锌。
Polyfunctional benzylic zinc chlorides by the direct insertion of magnesium into benzylic chlorides in the presence of LiCl and ZnCl2.
作者信息
Metzger Albrecht, Piller Fabian M, Knochel Paul
机构信息
Department Chemie und Biochemie, Ludwig-Maximilians-Universität, München Butenandtstr. 5-13, D-81377 München, Germany.
出版信息
Chem Commun (Camb). 2008 Nov 30(44):5824-6. doi: 10.1039/b812396a. Epub 2008 Oct 1.
DOI:10.1039/b812396a
PMID:19009094
Abstract
Benzylic zinc chlorides bearing various functional groups are smoothly prepared by the direct insertion of magnesium into benzylic chlorides in the presence of LiCl and ZnCl(2).
摘要
通过在氯化锂和氯化锌存在下将镁直接插入苄基氯中，可以顺利制备带有各种官能团的苄基氯化锌。
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