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单壁碳纳米管内一维碘化亚铜晶体的结构。

The structure of 1D CuI crystals inside SWNTs.

作者信息

Kiselev N A, Zakalyukin R M, Zhigalina O M, Grobert N, Kumskov A S, Grigoriev Yu V, Chernysheva M V, Eliseev A A, Krestinin A V, Tretyakov Yu D, Freitag B, Hutchison J L

机构信息

Institute of Crystallography RAS, Moscow, 119333, Russia.

出版信息

J Microsc. 2008 Nov;232(2):335-42. doi: 10.1111/j.1365-2818.2008.02104.x.

Abstract

Nanocomposites consisting of one-dimensional CuI crystals inside single-walled carbon nanotubes were obtained using the capillary technique. high-resolution transmission electron microscopy investigations of the atomic structure of the encapsulated 1D CuI crystals revealed two types of 1D CuI crystals with growth direction <001> and <110> relative to the bulk hexagonal CuI structure. Atomic structure models were proposed based on the high-resolution transmission electron microscopy images. According to the proposed models and image simulations, the main contrast in the 1D crystal images arises from the iodine atoms whereas copper atoms, with lower atomic number giving lower contrast, are thought to be statistically distributed.

摘要

采用毛细管技术制备了由单壁碳纳米管内的一维碘化亚铜晶体组成的纳米复合材料。对封装的一维碘化亚铜晶体的原子结构进行的高分辨率透射电子显微镜研究表明,相对于块状六方碘化亚铜结构,存在两种生长方向为<001>和<110>的一维碘化亚铜晶体。基于高分辨率透射电子显微镜图像提出了原子结构模型。根据所提出的模型和图像模拟,一维晶体图像中的主要对比度来自碘原子,而原子序数较低、对比度较低的铜原子被认为是统计分布的。

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