一个具有混合自旋结构且在自旋转变与磁相互作用之间存在协同效应的铁（II）自旋交叉簇合物。
A spin-crossover cluster of iron(II) exhibiting a mixed-spin structure and synergy between spin transition and magnetic interaction.
作者信息
Wu Da-Yu, Sato Osamu, Einaga Yasuaki, Duan Chun-Ying
机构信息
Kyushu University, Institute for Materials Chemistry and Engineering, 6-1 Kasuga, 816-8580, Fukuoka, Japan.
出版信息
Angew Chem Int Ed Engl. 2009;48(8):1475-8. doi: 10.1002/anie.200804529.
How low can you go? An Fe(II) (4) square was prepared by self-assembly and exhibits both thermally induced and photoinduced spin crossover from a system with four high-spin (HS) centers to one with two high-spin and two low-spin (LS) centers. The spin-crossover sites are located on the same side of the square, and the spin transition and magnetic interactions (see picture) are synergistically coupled.
你能降到多低？通过自组装制备了一个Fe(II) (4) 正方形，它展现出从一个具有四个高自旋（HS）中心的体系到一个具有两个高自旋和两个低自旋（LS）中心的体系的热诱导和光诱导自旋交叉。自旋交叉位点位于正方形的同一侧，并且自旋转变和磁相互作用（见图）是协同耦合的。
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