氟化芳烃溶剂对常见烯烃复分解催化剂性能的掺杂效应：在生物活性化合物制备中的应用
The doping effect of fluorinated aromatic hydrocarbon solvents on the performance of common olefin metathesis catalysts: application in the preparation of biologically active compounds.
作者信息
Samojłowicz Cezary, Bieniek Michał, Zarecki Andrzej, Kadyrov Renat, Grela Karol
机构信息
Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.
出版信息
Chem Commun (Camb). 2008 Dec 21(47):6282-4. doi: 10.1039/b816567j. Epub 2008 Oct 22.
DOI:10.1039/b816567j
PMID:19048129
Abstract
Aromatic fluorinated hydrocarbons, used as solvents for olefin metathesis reactions, catalysed by standard commercially available Ru precatalysts, allow substantially higher yields to be obtained, especially of challenging substrates, including natural and biologically active compounds.
摘要
芳族氟代烃用作烯烃复分解反应的溶剂，在市售标准钌预催化剂的催化下，能显著提高产率，尤其是对于具有挑战性的底物，包括天然和生物活性化合物。
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