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Formation of dodecaphenylporphodimethene via facile protonation of saddle-distorted dodecaphenylporphyrin.

作者信息

Kojima Takahiko, Hanabusa Kakeru, Ohkubo Kei, Shiro Motoo, Fukuzumi Shunichi

机构信息

Department of Material and Life Science, Osaka University, Suita, Osaka 565-0871, Japan.

出版信息

Chem Commun (Camb). 2008 Dec 28(48):6513-5. doi: 10.1039/b816063e. Epub 2008 Nov 5.

DOI:10.1039/b816063e
PMID:19057763
Abstract

A saddle-distorted dodecaphenylporphyrin undergoes protonation followed by two-electron reduction by SnCl(2) to give a roof-shaped dodecaphenylporphodimethene which exhibits reversible one-electron reduction and oxidation behaviour in benzonitrile to allow us to observe an ESR spectrum of pi-cation radical in the course of electrochemical oxidation.

摘要

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