Scott Thomas A, Ooro Betty A, Collins David J, Shatruk Michael, Yakovenko Andrey, Dunbar Kim R, Zhou Hong-Cai
Department of Chemistry and Biochemistry, Miami University, Oxford, OH 45056, USA.
Chem Commun (Camb). 2009 Jan 7(1):65-7. doi: 10.1039/b815272a. Epub 2008 Nov 20.
Two common radical anion reductants, potassium benzophenone ketyl (K(Ph(2)CO)) and potassium naphthalenide (K(2)(C(10)H(8))(2)(THF)), have been isolated and characterized for the first time in solvent-free form or with low solvent content, allowing their use as pure solid reactants in preparative redox chemistry in accurate stoichiometric amounts.
两种常见的自由基阴离子还原剂，二苯甲酮钾自由基阴离子（K(Ph(2)CO)）和萘化钾（K(2)(C(10)H(8))(2)(THF)），首次以无溶剂形式或低溶剂含量形式被分离和表征，这使得它们能够以精确的化学计量比作为纯固体反应物用于制备性氧化还原化学中。
