用于有效氧化反应的Ti-MCM-68的合成及其催化性能
Synthesis and catalytic performance of Ti-MCM-68 for effective oxidation reactions.
作者信息
Kubota Yoshihiro, Koyama Yoshihito, Yamada Taku, Inagaki Satoshi, Tatsumi Takashi
机构信息
Division of Materials Science and Chemical Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan.
出版信息
Chem Commun (Camb). 2008 Dec 14(46):6224-6. doi: 10.1039/b814286f. Epub 2008 Oct 14.
DOI:10.1039/b814286f
PMID:19082127
Abstract
Microporous titanosilicate Ti-MCM-68 (Ti-MSE) was successfully synthesized by post-synthetic isomorphous substitution of Ti for Al and proved to be a high-performance catalyst, in particular showing superior performance to TS-1, Ti-BEA, and Ti-MWW for phenol oxidation using H(2)O(2) as an oxidant.
摘要
通过Ti对Al的后合成同晶取代成功合成了微孔钛硅酸盐Ti-MCM-68（Ti-MSE），并证明其是一种高性能催化剂，特别是在使用H₂O₂作为氧化剂进行苯酚氧化时，表现出优于TS-1、Ti-BEA和Ti-MWW的性能。
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