SMN/INGAP/Department of Chemistry, University of Oslo, Sem Selands vei 26, 0315 Oslo, Norway.
Chem Commun (Camb). 2011 Nov 21;47(43):11867-9. doi: 10.1039/c1cc15175d. Epub 2011 Oct 5.
A new zeotype titanium silicate oxidation catalyst with the STT topology has been synthesized from direct synthesis. Ti-STT has a microporous structure with small pore openings, allowing shape selective oxidation catalysis. The isomorphous substitution of Si by Ti in the framework has been confirmed by Raman, FT-IR, UV-VIS and XANES spectroscopies.
一种新型的沸石型钛硅酸盐氧化催化剂采用直接合成法合成。Ti-STT 具有微孔结构,微孔开口较小,允许形状选择性氧化催化。通过拉曼、FT-IR、UV-VIS 和 XANES 光谱证实了骨架中 Si 被 Ti 的同晶取代。