伯氨基酸锂盐作为异丁醛与β-硝基烯烃不对称迈克尔加成反应的催化剂。
Primary amino acid lithium salt as a catalyst for asymmetric Michael addition of isobutyraldehyde with beta-nitroalkenes.
作者信息
Sato Atsushi, Yoshida Masanori, Hara Shoji
机构信息
Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University, Sapporo, 060-8628, Japan.
出版信息
Chem Commun (Camb). 2008 Dec 14(46):6242-4. doi: 10.1039/b814804j. Epub 2008 Oct 16.
DOI:10.1039/b814804j
PMID:19082133
Abstract
Phenylalanine lithium salt was found to be an effective catalyst for asymmetric Michael addition of isobutyraldehyde with beta-nitroalkenes to give quaternary carbon-containing nitroalkanes.
摘要
发现苯丙氨酸锂盐是一种有效的催化剂，可用于异丁醛与β-硝基烯烃的不对称迈克尔加成反应，以生成含季碳的硝基烷烃。
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