Rakowski DuBois M, DuBois Daniel L
Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Richland, WA 99352, USA.
Chem Soc Rev. 2009 Jan;38(1):62-72. doi: 10.1039/b801197b. Epub 2008 Nov 6.
This tutorial review describes the development of discrete transition metal complexes as electrocatalysts for H2 formation and oxidation. The approach involves the study of thermodynamic properties of metal hydride intermediates and the design of ligands that incorporate proton relays. The work is inspired by structural features of the H2ase enzymes and should be of interest to researchers in the areas of biomimetic chemistry as well as catalyst design and hydrogen utilization.
本教程综述描述了离散过渡金属配合物作为用于氢气生成和氧化的电催化剂的发展情况。该方法涉及研究金属氢化物中间体的热力学性质以及设计包含质子中继体的配体。这项工作受到氢化酶的结构特征启发，对于仿生化学以及催化剂设计和氢利用领域的研究人员来说应该会很感兴趣。
