用于化学储氢的硼氮化合物。

B-N compounds for chemical hydrogen storage.

作者信息

Hamilton Charles W, Baker R Tom, Staubitz Anne, Manners Ian

机构信息

Los Alamos National Laboratory, Inorganic, Isotope, and Actinide Chemistry, MS J582, Los Alamos, NM 87545, USA.

出版信息

Chem Soc Rev. 2009 Jan;38(1):279-93. doi: 10.1039/b800312m. Epub 2008 Nov 26.

DOI:10.1039/b800312m

PMID:19088978

Abstract

Hydrogen storage for transportation applications requires high volumetric and gravimetric storage capacity. B-N compounds are well suited as storage materials due to their light weight and propensity for bearing multiple protic (N-H) and hydridic (B-H) hydrogens. This critical review briefly covers the various methods of hydrogen storage, and then concentrates on chemical hydrogen storage using B-N compounds. The simplest B-N compound, ammonia borane (H3NBH3), which has a potential 19.6 wt% hydrogen storage capacity, will be emphasised (127 references).

摘要

用于交通运输的储氢需要具备高体积储氢容量和高重量储氢容量。硼氮化合物因其重量轻且易于承载多个质子性（N-H）和氢负离子性（B-H）氢原子，非常适合作为储氢材料。本综述简要介绍了各种储氢方法，然后重点关注使用硼氮化合物的化学储氢。将着重介绍最简单的硼氮化合物氨硼烷（H3NBH3），其潜在储氢容量可达19.6 wt%（参考文献127篇）。