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[傅里叶变换红外光谱非线性多点校准方法的研究]

[Study on the method of FTIR spectrum non linear multiple point calibration].

作者信息

Liu Zhi-ming, Gao Min-guang, Liu Wen-qing, Lu Yi-huai, Zhang Tian-shu, Xu Liang, Wei Xiu-li

机构信息

Key Lab of Environment Optics & Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2008 Sep;28(9):2077-80.

Abstract

FTIR Technique has developed rapidly since 1980s, and has become increasingly important. It has been used in a variety of fields. In order to make sure the result is of nicety, the authors should manipulate the FTIR spectrometer accurately and study its instrument response function and calibration arithmetic. Because the instrument response of the detector of FTIR spectrometer is different at different wave band, the no-calibrated spectrum was ruleless. Without calibration, we can not obtain the absolute intensity, even relative intensity. There are two calibration arithmetics: Linear calibration arithmetic corresponding linear detector and non-calibration arithmetic corresponding non-linear detector. The present paper gave the arithmetic of linear calibration and non-linear multiple point calibration. The authors measured several blackbody spectra at some different temperatures. Some of them were used for calibration and one was used to test the result of calibration The result indicated that this method of non-linear multiple point calibration was very good. The relative arbitrary between calibrated blackbody spectrum and standard blackbody spectrum was near 0.2%, while the maximum was still lower than 0.4%.

摘要

自20世纪80年代以来,傅里叶变换红外光谱(FTIR)技术发展迅速,且变得越来越重要。它已被应用于各种领域。为确保结果的准确性,作者应精确操作FTIR光谱仪,并研究其仪器响应函数和校准算法。由于FTIR光谱仪探测器的仪器响应在不同波段有所不同,未经校准的光谱是无规律的。未经校准,我们无法获得绝对强度,甚至相对强度。有两种校准算法:对应线性探测器的线性校准算法和对应非线性探测器的非校准算法。本文给出了线性校准和非线性多点校准算法。作者测量了几个不同温度下的黑体光谱。其中一些用于校准,一个用于测试校准结果。结果表明,这种非线性多点校准方法非常好。校准后的黑体光谱与标准黑体光谱之间的相对偏差接近0.2%,而最大值仍低于0.4%。

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