从格氏菌属（肉座菌目，子囊菌门）中分离出光学活性的西多酸及其绝对立体化学结构。

Isolation and absolute stereochemistry of optically active sydonic acid from Glonium sp. (Hysteriales, Ascomycota).

作者信息

Kudo Shinji, Murakami Takanori, Miyanishi Junsuke, Tanaka Kazuaki, Takada Noboru, Hashimoto Masaru

机构信息

Faculty of Agriculture and Life Science, Hirosaki University.

出版信息

Biosci Biotechnol Biochem. 2009 Jan;73(1):203-4. doi: 10.1271/bbb.80535. Epub 2009 Jan 7.

DOI:10.1271/bbb.80535

PMID:19129640

Abstract

Optically active sydonic acid (1) was isolated for the first time from a culture broth of Glonium sp. The absolute stereochemistry was established to be (S) by comparing the circular dichroism (CD) spectrum with that of (+)-curcutetraol after conversion into (+)-sydonol (2).

摘要

旋光性的西多酸（1）首次从Glonium sp.的培养液中分离得到。通过将其转化为（+）-西多醇（2）后，将其圆二色性（CD）光谱与（+）-curcutetraol的光谱进行比较，确定其绝对立体化学结构为（S）型。